Cracks mainly propagate along random high angle grain boundaries in cold worked 316l. Dunn3, and mekonen bayssieand mekonen bayssie3 1center for nuclear waste regulatory analyses 2southwest research institute san antonio, texas 3u. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Chloride stress corrosion cracking clscc is one the most common reasons. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Effect of chloride deposition on stress corrosion cracking. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. External chloride stress corrosion cracking of stainless. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The molybdenum gives 316 better overall corrosion resistant properties than grade 304, particularly higher resistance to pitting and crevice corrosion in chloride environments. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution.
Chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s. Cold work of materials, dissolved oxygen and chloride in water. Higher temperatures and reduced ph will increase the probability of scc. Addition of oxygen in autoclaves promoted the tendency to stress corrosion cracking. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Although the type 316 alloy is somewhat more resistant to scc than the 18 cr8 ni alloys because of the molybdenum content, they still are quite susceptible.
Conventional stainless steels such as 304l and 316l are susceptible to chloride stress corrosion cracking ssc under certain conditions. Show full abstract to chloride stress corrosion cracking and higher strength levels than type 300 series austenitic stainless steels. This material is susceptible to stress corrosion cracking in sour brines, and thus the use of this material is restricted according to the limits detailed in iso 15156nace mr0175, which are detailed in table 1. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels.
Stress corrosion cracking of the aisi 316l stainless steel haz in a pwr nuclear reactor environment. Effects of chloride and oxygen on stress corrosion. Stress corrosion cracking austenitic stainless steels are susceptible to stress corrosion cracking scc in halide environments. Sour service limits of dualcertified 316316l steel twi.
Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s. Stress corrosion cracking of the aisi 316l stainless steel. This safety alert highlights the issue of chloride stress corrosion cracking of stainless steel lokring pipe connectors and advises dutyholders on actions required. Stress corrosion cracking scc is dangerous because it can destroy a component at stress levels below the yield strength of an alloy. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking facts and how to reduce the risk. In the presence of chloride ions, austenitic stainless steels are susceptible to scc. Scc is known as an insidious form of corrosion failure and. Stress corrosion cracking of sensitized type 304 stainless.
In these media, many stainless steel grades suffer from crevice corrosion, pitting corrosion and stress corrosion. Stress corrosion cracking of an austenitic stainless steel in. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Environmental effects on stress corrosion cracking of type 316l. Stress corrosion cracking behavior of nickel base alloys. Chlorideinduced stress corrosion cracking of 316 stainless. The objective of this work is to evaluate if atmospheric stress corrosion cracking can develop in stainless steel cask. Stainless steel 316 and 316l grade 316 is the standard molybdenumbearing grade, second inoverall volume production to 304 amongst the austenitic stainless steels. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses.
Effects of marine environments on stress corrosion. This study is to identify factors responsible for loss of production due to problems in plant and equipment. This diagram figure 1 is analogous to a similar diagram for caustic. Stress corrosion cracking of an austenitic stainless steel. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. The occurrence of atmosphericinduced chloride stress corrosion cracking in types 304l and 316l stainless steels contacted with seasalt and magnesium chloride deposits has been studied under. Environmental factors in the stress corrosion cracking of.
Alloy 904l is a superaustenitic stainless steel that is designed for moderate to high corrosion resistance in a wide range of process environments. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Duplex stainless steels are far less prone to this type of corrosion. Stress corrosion cracking in chloride containing media. Environmental factors in the stress corrosion cracking of type 316l stainless steel and alloy 825 in chloride solutions g. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Cragnolino 1 center for nuclear waste regulatory analyses. Effect of chloride deposition on stress corrosion cracking of 316l.
Pdf atmosphericinduced stress corrosion cracking of austenitic. An example is hot potable water under heat transfer conditions which permit chlorides to. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stress corrosion cracking facts and how to reduce the. Therefore, standard grades such as 304304l and 316316l are very susceptible to this mode of attack. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. The morphology of the scc zone in the 316 is nearly 100%. Pdf the occurrence of atmosphericinduced chloride stress corrosion cracking in types 304l and 316l stainless steels contacted with seasalt and. Chloride stress corrosion cracking is a well known form of scc, typically caused by inadvertently contaminating equipment with chlorides. Although the type 316 alloy is somewhat more resistant to scc than the 18 cr. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This paper presents the effect of buffing on the stress corrosion cracking scc resistance of machined surfaces of aisi 316l stainless steel ss.
The occurrence of atmosphericinduced chloride stress corrosion cracking in types 304l and 316l stainless steels contacted with seasalt and magnesium chloride deposits has been studied under controlled conditions of relative humidity ca. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Because many of the dry storage containers are made of austenitic stainless steels, a potential concern is the susceptibility of the canisters to undergo chloride induced stress corrosion cracking. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. For austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. Effects of chloride and oxygen on stress corrosion cracking of cold.
Effects of chloride and oxygen on stress corrosion cracking. With its highly alloyed chemistry 25% nickel and 4. May 27, 2011 for austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Some 95% of 316l chemical plant equipment failures may be attributed to chloride scc. Stress corrosion cracking scc is the cracking induced from the combined influence of. Susceptible alloys include 304l, 316l, 321, and 347. Chloride stress corrosion cracking in austenitic stainless steel. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern.
Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc is characterized by cracks propagating either. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This safety alert highlights the issue of chloride stress corrosion cracking which has been found to affect stainless steel grade 316 316l lokring pipe connectors.
In all cases of failure by stress corrosion cracking, the following three factors must be present. Therefore, it is important to determine the longterm general corrosion rates and susceptibility to localized corrosion and stress corrosion cracking of 316l stainless steel under various service conditions. The standard austenitic steels of the astm 304l and astm 316l types are prone to stress corrosion cracking scc in chloride bearing solutions at temperatures above 60 c 140 f. Scc is known as an insidious form of corrosion failure and it results in a significant drop in the mechanical strength only with little metal loss. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. Cragnolino 1 center for nuclear waste regulatory analyses, southwest research institute, 6220 culebra road, san antonio, tx, 782385166. Methods of minimizing chloride stress corrosion cracking. The incubation time for stress corrosion cracking can be very short, sometimes measured in hours. Materials free fulltext stress corrosion cracking of an. Chloride stresscorrosion cracking scc is one of the most serious forms of localized corrosion. Stress corrosion cracking in 316l stainless steel bellows. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking scc is a common issue with many specialty alloys. Controlling chloride induced stress corrosion cracking of aisi 316l. Types of corrosion materials selection guide swagelok. Although no stainless steel grade is totally immune. Mintz1, leonardo caseres2, darrell s dunndarrell s. Materials free fulltext stress corrosion cracking of. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. Chloride stress corrosion cracking and 316 stainless steel. The standard austenitic steels of the astm 304l and astm 316l types are prone to stress corrosion cracking scc in chloride bearing solutions at temperatures. Corrosion of stainless steel type 316l in a seepage water.
An example is hot potable water under heat transfer conditions which permit chlorides to concentrate locally. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 sinduced scc. The standard 304304l and 316 316l grades are most susceptible. A precursor of stress corrosion cracking in chloridebearing environments is. Pdf stress corrosion cracking of austenitic stainless. Therefore, it is important to determine the longterm general corrosion rates and susceptibility to localized corrosion. The standard 304304l and 316316l grades are most susceptible. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Pdf atmosphericinduced stress corrosion cracking of.
A corrosive medium especially chloride bearing or hydrogensulphide h 2 s media. Apr 14, 2015 this safety alert highlights the issue of chloride stress corrosion cracking of stainless steel lokring pipe connectors and advises dutyholders on actions required. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Mechanisms of stresscorrosion cracking asm international. Stress corrosion cracking in 316l stainless steel bellows of. Pipe elbows are made by hot bending these pipe lengths in a. Effects of marine environments on stress corrosion cracking. The chief applications of hastelloy alloys are in the presence of hot chloride solutions. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. The morphology of the scc zone in the 316 is nearly 100% intergranular cracking while the 316l specimen shows predominantly intergranular cracking accompanied by some transgranular cracking. The use of this stainless steel grade in chloride containing environments is not normally. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries.
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